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Tracing the impact of stack configuration on interface resistances in reverse electrodialysis by in situ electrochemicalimpedance spectroscopy

《环境科学与工程前沿（英文）》 2022年 第16卷 第4期 doi: 10.1007/s11783-021-1480-9

摘要：

• RED performance and stack resistance were studied by EIS and LSV.

关键词： Reverse electrodialysis     Electrochemical impedance spectroscopy     Concentration polarization     Spacer shadow effect    

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SOFC关键材料电化学表征方法

樊丽权,赵二庆,高克卿,熊岳平

《中国工程科学》 2013年 第15卷 第2期   页码 50-56

摘要：

固体氧化物燃料电池（SOFC）是全固态的化学发电装置，其构成材料固体氧化物对SOFC性能的影响尤为重要。本文从材料对SOFC电化学性能影响的视角出发，立足电化学、固体电化学的基本原理，概述了SOFC构成材料的电化学表征方法，并将一些研究积累赘述文中，希望有利于材料的进一步研究。

关键词： 固体氧化物材料     直流极化     交流阻抗     SOFC    

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Spectral element modeling based structure piezoelectric impedance computation and damage identification

Zhigang GUO, Zhi SUN

《结构与土木工程前沿（英文）》 2011年 第5卷 第4期   页码 458-464 doi: 10.1007/s11709-011-0133-7

摘要： This paper presents a numerical simulation study on electromechanical impedance technique for structural damage identification. The basic principle of impedance based damage detection is structural impedance will vary with the occurrence and development of structural damage, which can be measured from electromechanical admittance curves acquired from PZT patches. Therefore, structure damage can be identified from the electromechanical admittance measurements. In this study, a model based method that can identify both location and severity of structural damage through the minimization of the deviations between structural impedance curves and numerically computed response is developed. The numerical model is set up using the spectral element method, which is promised to be of high numerical efficiency and computational accuracy in the high frequency range. An optimization procedure is then formulated to estimate the property change of structural elements from the electric admittance measurement of PZT patches. A case study on a pin-pin bar is conducted to investigate the feasibility of the proposed method. The results show that the presented method can accurately identify bar damage location and severity even when the measurements are polluted by 5% noise.

关键词： PZT     piezoelectric impedance     optimization     spectral element     damage identification    

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Electrochemical performance of thermally-grown SiO

X. D. HUANG, X. F. GAN, Q. A. HUANG, J. Z. YANG

《能源前沿（英文）》 2018年 第12卷 第2期   页码 225-232 doi: 10.1007/s11708-018-0556-0

摘要： Direct integration of lithium-ion battery (LIB) with electronic devices on the same Si substrate can significantly miniaturize autonomous micro systems. For achieving direct integration, a barrier layer is essential to be inserted between LIB and the substrate for blocking Li diffusion. In this paper, the feasibility of thermal SiO film as the barrier layer is investigated by electrochemical characterization and X-ray photoelectron spectroscopy (XPS). Due to the negligible side reactions of thermal SiO with electrolyte, the solid electrolyte interphase (SEI) layer formed on the surface of the barrier layer is thin and the SEI content mainly consists of hydrocarbon together with slight polyethylene oxide (PEO), Li PO F , and Li CO . Although 8-nm thermal SiO effectively prevents the substrate from alloying with Li , the whole film changes to Li silicate after electrochemical cycling due to the irreversible chemical reactions of SiO with electrolyte. This degrades the performance of the barrier layer against the electrolyte penetration, thus leading to the existence of Li (in the form of F-Si-Li) and solvent decompositions (with the products of hydrocarbon and PEO) near the barrier layer/substrate interface. Moreover, it is found that the reaction kinetics of thermal SiO with electrolyte decrease significantly with increasing the SiO thickness and no reactions are found in the bulk of the 30-nm SiO film. Therefore, thermal SiO with an appropriate thickness is a promising barrier layer for direct integration.

关键词： autonomous micro system     direct integration     barrier layer     thermal SiO2 film     X-ray photoelectron spectroscopy (XPS)    

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Recent advances in electrochemical decontamination of perfluorinated compounds from water: a review

《环境科学与工程前沿（英文）》 2023年 第17卷 第2期 doi: 10.1007/s11783-023-1618-z

摘要：

● Recent advances in the electrochemical decontamination of PFAS are reviewed.

关键词： Perfluorinated compounds     Electrochemical approach     Working mechanisms     Impacting factor     Coupled process    

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Fuzzy force control of constrained robot manipulators based on impedance model in an unknown environment

LIU Hongyi, WANG Fei, WANG Lei

《机械工程前沿（英文）》 2007年 第2卷 第2期   页码 168-174 doi: 10.1007/s11465-007-0028-4

摘要： To precisely implement the force control of robot manipulators in an unknown environment, a control strategy based on fuzzy prediction of the reference trajectory in the impedance model is developed. The force tracking experiments are executed in an open-architecture control system with different tracking velocities, different desired forces, different contact stiffnesses and different surface figurations. The corresponding force control results are compared and analyzed. The influences of unknown parameters of the environment on the contact force are analyzed based on experimental data, and the tunings of predictive scale factors are illustrated. The experimental results show that the desired trajectory in the impedance model is predicted exactly and rapidly in the cases that the contact surface is unknown, the contact stiffness changes, and the fuzzy force control algorithm has high adaptability to the unknown environment.

关键词： predictive     tracking     corresponding     stiffness     algorithm    

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Factors influencing near infrared spectroscopy analysis of agro-products: a review

Xiao XU, Lijuan XIE, Yibin YING

《农业科学与工程前沿（英文）》 2019年 第6卷 第2期   页码 105-115 doi: 10.15302/J-FASE-2019255

摘要：

The near infrared (NIR) spectroscopy technique has wide applications in agriculture with the advantages of being nondestructive, sensitive, safe and rapid. However, there are still more than 40 error sources influencing the robustness and accuracy of its calibration and operation. Environmental, sample and instrument factors that influence the analysis are discussed in this review, including temperature, humidity and other factors that introduce uncertainty. Error sources from livestock products, fruit and vegetables, which are the most common objects in the field of NIR analysis, are also emphasized in the second part. In addition, studies utilizing different instruments, spectral pretreatments, variable selection methods, wavelength ranges, detection modes and calibration methods are tabulated to illustrate the complications they introduce and how they influence NIR analysis. It is suggested that large scale of data with abundant varieties can be used to build a more robust calibration model, in order to improve the robustness and accuracy of the NIR analytical model, and overcome problems caused by confining analysis to too many uniform samples.

关键词： agro-product     error source     influence factor     near infrared spectroscopy    

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Detection of void and metallic inclusion in 2D piezoelectric cantilever beam using impedance measurements

S. SAMANTA, S. S. NANTHAKUMAR, R. K. ANNABATTULA, X. ZHUANG

《结构与土木工程前沿（英文）》 2019年 第13卷 第3期   页码 542-556 doi: 10.1007/s11709-018-0496-0

摘要： The aim of current work is to improve the existing inverse methodology of void-detection based on a target impedance curve, leading to quick-prediction of the parameters of single circular void. In this work, mode-shape dependent shifting phenomenon of peaks of impedance curve with change in void location has been analyzed. A number of initial guesses followed by an iterative optimization algorithm based on univariate method has been used to solve the problem. In each iteration starting from each initial guess, the difference between the computationally obtained impedance curve and the target impedance curve has been reduced. This methodology has been extended to detect single circular metallic inclusion in 2D piezoelectric cantilever beam. A good accuracy level was observed for detection of flaw radius and flaw-location along beam-length, but not the precise location along beam-width.

关键词： piezoelectricity     impedance curve     mode shapes     inverse problem     flaw detection     curve shifting    

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Review: Tip-based vibrational spectroscopy for nanoscale analysis of emerging energy materials

Amun JARZEMBSKI, Cedric SHASKEY, Keunhan PARK

《能源前沿（英文）》 2018年 第12卷 第1期   页码 43-71 doi: 10.1007/s11708-018-0524-8

摘要： Vibrational spectroscopy is one of the key instrumentations that provide non-invasive investigation of structural and chemical composition for both organic and inorganic materials. However, diffraction of light fundamentally limits the spatial resolution of far-field vibrational spectroscopy to roughly half the wavelength. In this article, we thoroughly review the integration of atomic force microscopy (AFM) with vibrational spectroscopy to enable the nanoscale characterization of emerging energy materials, which has not been possible with far-field optical techniques. The discussed methods utilize the AFM tip as a nanoscopic tool to extract spatially resolved electronic or molecular vibrational resonance spectra of a sample illuminated by a visible or infrared (IR) light source. The absorption of light by electrons or individual functional groups within molecules leads to changes in the sample’s thermal response, optical scattering, and atomic force interactions, all of which can be readily probed by an AFM tip. For example, photothermal induced resonance (PTIR) spectroscopy methods measure a sample’s local thermal expansion or temperature rise. Therefore, they use the AFM tip as a thermal detector to directly relate absorbed IR light to the thermal response of a sample. Optical scattering methods based on scanning near-field optical microscopy (SNOM) correlate the spectrum of scattered near-field light with molecular vibrational modes. More recently, photo-induced force microscopy (PiFM) has been developed to measure the change of the optical force gradient due to the light absorption by molecular vibrational resonances using AFM’s superb sensitivity in detecting tip-sample force interactions. Such recent efforts successfully breech the diffraction limit of light to provide nanoscale spatial resolution of vibrational spectroscopy, which will become a critical technique for characterizing novel energy materials.

关键词： vibrational spectroscopy     atomic force microscopy     photo-thermal induced resonance     scanning near-field optical microscopy     tip-enhanced Raman spectroscopy     photo-induced force microscopy     molecular resonances     surface phonon polaritons     energy materials    

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Research progress in tribo-electrochemistry and tribo-electrochemical polishing

ZHAI Wenjie

《机械工程前沿（英文）》 2007年 第2卷 第4期   页码 463-467 doi: 10.1007/s11465-007-0080-0

摘要： In this paper, the status quo and recent progress in the research on tribo-electrochemistry in aqueous and non-aqueous media, respectively, are reviewed. Much more attention has been paid to the tribo-electrochemical mechanisms for the control of friction and wear. Based on a summary of the conventional polishing principles of hard and brittle materials, the tribo-electrochemical polishing method is proposed. The results of the preliminary test show that tribo-electrochemical polishing is promising to become a critical technology in the high efficient polishing and planarization of microelectronic materials.

关键词： tribo-electrochemical mechanisms     planarization     non-aqueous     tribo-electrochemistry     summary    

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Terahertz time-domain spectroscopy of high-pressure flames

Jason BASSI, Mark STRINGER, Bob MILES, Yang ZHANG

《能源前沿（英文）》 2009年 第3卷 第2期   页码 123-133 doi: 10.1007/s11708-009-0033-x

摘要： Laser spectroscopy in the visible and near infrared is widely used as a diagnostic tool for combustion devices, but this approach is difficult at high pressures within a sooty flame itself. High soot concentrations render flames opaque to visible light, but they remain transparent to far-infrared or terahertz (THz) radiation. The first far-infrared absorption spectra, to the best of our knowledge, of sooty, non-premixed, ethylene high-pressure flames covering the region of 0.2-2.5 THz is presented. A specially designed high-pressure burner which is optically accessible to THz radiation has been built allowing flame transmission measurements up to pressures of 1.6 MPa. Calculations of the theoretical combustion species absorption spectra in the 0.2-3 THz range have shown that almost all the observable features arise from H O. A few OH (1.84 and 2.51 THz), CH (2.58 THz), and NH (1.77 and 2.95 THz) absorption lines are also observable in principle. A large number of H O absorption lines are observed in the ground vibrational in a laminar non-premixed, sooty flame (ethylene) at pressures up to 1.6 MPa.

关键词： terahertz time-domain spectroscopy     high-pressure flames     H2O absorption lines    

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Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1440-1449 doi: 10.1007/s11705-023-2333-9

摘要： The composite electrode of CoNiSx and Ti3C2Tx MXene was successfully prepared using a one-step hydrothermal method under the in-situ doping of the cobalt element. The effects of in-situ doping of the cobalt element on the micromorphology and electrochemical performance of the electrodes were investigated. After in-situ doping of the cobalt element, NiS with a needle-like structure was converted into a CoNiSx with petal-like structure. The petal-like CoNiSx with a rough surface was very dense and evenly wrapped on the surface and interlamination of Ti3C2Tx, which helped increase the specific surface area and pore volume of the electrode. Under the identical test conditions, CoNiSx@Ti3C2Tx had a higher specific capacitance and capacitance retention than NiS@Ti3C2Tx. This result indicated that the in-situ doping of the cobalt element promoted the electrochemical performance of the electrode. The energy density of the CoNiSx@Ti3C2Tx/nickel foam (NF)//activated carbon (AC)/NF asymmetric supercapacitor device was 59.20 Wh·kg–1 at a power density of 826.73 W·kg–1, which was much higher than that of NiS@Ti3C2Tx/NF//AC/NF. Three CoNiSx@Ti3C2Tx/NF//AC/NF in series were able to illuminate the light emitting diode lamp for about 10 min, which was higher than the 5 min of three NiS@Ti3C2Tx/NF//AC/NF in series under the same condition. The CoNiSx@Ti3C2Tx/NF//AC/NF with high energy density had better application potential in energy storage than the NiS@Ti3C2Tx/NF//AC/NF.

关键词： MXene     supercapacitor     cobalt doping     structure characterization     electrochemical performance    

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Modeling of oil near-infrared spectroscopy based on similarity and transfer learning algorithm

Yifei Wang, Kai Wang, Zhao Zhou, Wenli Du

《化学科学与工程前沿（英文）》 2019年 第13卷 第3期   页码 599-607 doi: 10.1007/s11705-019-1807-2

摘要： Near-infrared spectroscopy mainly reflects the frequency-doubled and total-frequency absorption information of hydrogen-containing groups (O‒H, C‒H, N‒H, S‒H) in organic molecules for near-infrared lights with different wavelengths, so it is applicable to testing of most raw materials and products in the field of petrochemicals. However, the modeling process needs to collect a large number of laboratory analysis data. There are many oil sources in China, and oil properties change frequently. Modeling of each raw material is not only unfeasible but also will affect its engineering application efficiency. In order to achieve rapid modeling of near-infrared spectroscopy and based on historical data of different crude oils under different detection conditions, this paper discusses about the feasibility of the application of transfer learning algorithm and makes it possible that transfer learning can assist in rapid modeling using certain historical data under similar distributions under a small quantity of new data. In consideration of the requirement of transfer learning for certain similarity of different datasets, a transfer learning method based on local similarity feature selection is proposed. The simulation verification of spectral data of 13 crude oils measured by three different probe detection methods is performed. The effectiveness and application scope of the transfer modeling method under different similarity conditions are analyzed.

关键词： near-infrared spectroscopy     transfer learning     similarity     modeling    

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Effect of denitrifying bacteria on the electrochemical reaction of activated carbon fiber in electrochemical

YING Diwen, JIA Jinping, ZHANG Lehua

《环境科学与工程前沿（英文）》 2007年 第1卷 第3期   页码 305-310 doi: 10.1007/s11783-007-0051-z

摘要： An electrochemical-activated denitrifying biofilm system consisting of activated carbon fiber electrodes immobilized with denitrifying bacteria film as cathode was studied. A revised model for an electrochemical-activated denitrifying biofilm was developed and validated by electrochemical analysis of cathodal polarization curves and nitrate consumption rate. The cathodal polarization curve and nitrate consumption rate were introduced to verify the rate of electrochemical reaction and the activity of denitrifying bacteria, respectively. It was shown that the denitrification process effectively strengthened the electrochemical reaction while the electron also intensified denitrification activity. Electron was transferred between electrochemical process and biological process not only by hydrogen molecule but also by new produced active hydrogen atom. Additionally, a parameter of apparent exchange current density was deprived from the cathodal polarization curve with high overpotential, and a new bio-effect current density was defined through statistical analysis, which was linearly dependent to the activity of denitrification bacteria. Activated carbon fiber (ACF) electrode was also found to be more suitable to the electrochemical denitrifying system compared with graphite and platinum.

关键词： ACF     apparent exchange     hydrogen molecule     activated     biological process    

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Recent advances in the electrochemical oxidation water treatment: Spotlight on byproduct control

Yang Yang

《环境科学与工程前沿（英文）》 2020年 第14卷 第5期 doi: 10.1007/s11783-020-1264-7

摘要： Abstract • Byproduct formation mechanisms during electrochemical oxidation water treatment. • Control byproduct formation by quenchers. • Process optimization to suppress byproduct formation. Electrochemical oxidation (EO) is a promising technique for decentralized wastewater treatment, owing to its modular design, high efficiency, and ease of automation and transportation. The catalytic destruction of recalcitrant, non-biodegradable pollutants (per- and poly-fluoroalkyl substances (PFAS), pharmaceuticals, and personal care products (PPCPs), pesticides, etc.) is an appropriate niche for EO. EO can be more effective than homogeneous advanced oxidation processes for the degradation of recalcitrant chemicals inert to radical-mediated oxidation, because the potential of the anode can be made much higher than that of hydroxyl radicals (EOH = 2.7 V vs. NHE), forcing the direct transfer of electrons from pollutants to electrodes. Unfortunately, at such high anodic potential, chloride ions, which are ubiquitous in natural water systems, will be readily oxidized to chlorine and perchlorate. Perchlorate is a to-be-regulated byproduct, and chlorine can react with matrix organics to produce organic halogen compounds. In the past ten years, novel electrode materials and processes have been developed. However, spotlights were rarely focused on the control of byproduct formation during EO processes in a real-world context. When we use EO techniques to eliminate target contaminants with concentrations at μg/L-levels, byproducts at mg/L-levels might be produced. Is it a good trade-off? Is it possible to inhibit byproduct formation without compromising the performance of EO? In this mini-review, we will summarize the recent advances and provide perspectives to address the above questions.

关键词： Electrochemical water treatment     Byproducts     Perchlorate    

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标题 作者 时间 类型 操作

Tracing the impact of stack configuration on interface resistances in reverse electrodialysis by in situ electrochemicalimpedance spectroscopy

期刊论文

SOFC关键材料电化学表征方法

樊丽权,赵二庆,高克卿,熊岳平

期刊论文

Spectral element modeling based structure piezoelectric impedance computation and damage identification

Zhigang GUO, Zhi SUN

期刊论文

Electrochemical performance of thermally-grown SiO

X. D. HUANG, X. F. GAN, Q. A. HUANG, J. Z. YANG

期刊论文

Recent advances in electrochemical decontamination of perfluorinated compounds from water: a review

期刊论文

Fuzzy force control of constrained robot manipulators based on impedance model in an unknown environment

LIU Hongyi, WANG Fei, WANG Lei

期刊论文

Factors influencing near infrared spectroscopy analysis of agro-products: a review

Xiao XU, Lijuan XIE, Yibin YING

期刊论文

Detection of void and metallic inclusion in 2D piezoelectric cantilever beam using impedance measurements

S. SAMANTA, S. S. NANTHAKUMAR, R. K. ANNABATTULA, X. ZHUANG

期刊论文

Review: Tip-based vibrational spectroscopy for nanoscale analysis of emerging energy materials

Amun JARZEMBSKI, Cedric SHASKEY, Keunhan PARK

期刊论文

Research progress in tribo-electrochemistry and tribo-electrochemical polishing

ZHAI Wenjie

期刊论文

Terahertz time-domain spectroscopy of high-pressure flames

Jason BASSI, Mark STRINGER, Bob MILES, Yang ZHANG

期刊论文

Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element

期刊论文

Modeling of oil near-infrared spectroscopy based on similarity and transfer learning algorithm

Yifei Wang, Kai Wang, Zhao Zhou, Wenli Du

期刊论文

Effect of denitrifying bacteria on the electrochemical reaction of activated carbon fiber in electrochemical

YING Diwen, JIA Jinping, ZHANG Lehua

期刊论文

Recent advances in the electrochemical oxidation water treatment: Spotlight on byproduct control

Yang Yang

期刊论文